By Hongzhe Sun
Arsenic, antimony and bismuth, 3 similar parts of staff 15, are all present in hint amounts in nature and feature fascinating organic houses and makes use of. whereas arsenic is optimal as a poison - and certainly the illness of groundwater by way of arsenic is turning into an immense sickness in Asia - it additionally has makes use of for the remedy of blood melanoma and has lengthy been utilized in conventional chinese language drugs. Antimony and bismuth compounds are utilized in the health facility for the remedy of parasitic and bacterial infections.Biological Chemistry of Arsenic, Antimony and Bismuth is a vital evaluate of the organic chemistry of those 3 components, with contributions from a world panel of specialists. issues coated include:chemistry of As, Sb and Bibiological chemistry of arsenicbiological chemistry of Sb and Biarsenic and antimony speciation in environmental and organic samplesarsenic in conventional chinese language medicinearsenic in aquifersbiomethylation of As, Sb and Biuptake of metalloids through cellsbismuth complexes of porphyrins and their power in scientific applicationsHelicobacter pylori and bismuthmetabolism of arsenic trioxide in blood of the extreme promyelocytic leukemia patientsanticancer homes of As, Sb and Biradio-Bi in melanoma therapygenotoxicity of As, Sb and Bimetallomics as a brand new procedure for As, Sb and Bimetalloproteomics for As, Sb and BiBiological Chemistry of Arsenic, Antimony and Bismuth conveys the fundamental facets of the bioinorganic chemistry of those 3 parts, making this e-book a useful supplement to extra basic bioinorganic chemistry texts and extra really expert topical stories. it's going to discover a position at the bookshelves of practitioners, researchers and scholars operating in bioinorganic chemistry and medicinal chemistry.
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Additional info for Biological Chemistry of Arsenic, Antimony and Bismuth
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In the Meyer Reaction, alkylation of arsenic always results in a pentavalent, never a trivalent, arsenical product. Several animals (guinea pig, marmoset, tamarin and chimpanzee) are deficient in the capacity to methylate arsenic [62, 63]. Chimpanzees express an inactivated truncated arsenic methyltransferase enzyme . The sequential view of arsenic methylation of Arsenic’s Interactions with DNA and Proteins 29 arsenic in mammals is well covered by several review articles from the same experimental group [30, 56, 57, 64].
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Biological Chemistry of Arsenic, Antimony and Bismuth by Hongzhe Sun